Using the Rutherford model of the atom, derive the expression for the total energy of the electron in a hydrogen atom. What is the significance of the total negative energy possessed by the electron?
Answer:E=−2rke2; negative energy ⇒ electron is bound.
Solution
In the Rutherford model the Coulomb attraction supplies the centripetal force for the electron (charge −e) orbiting a nucleus of charge +e:
r2ke2=rmv2⇒mv2=rke2.
Kinetic energy: K=21mv2=2rke2. Potential energy: U=−rke2. Total energy:
E=K+U=2rke2−rke2=−2rke2.
The negative total energy means the electron is bound to the nucleus; energy must be supplied to remove it to infinity.