(a) State Bohr's postulate to define stable orbits in a hydrogen atom. How does de-Broglie's hypothesis explain the stability of these orbits? (b) A hydrogen atom initially in the ground state absorbs a photon which excites it to the n=4 level. Estimate the frequency of the photon.
Answer:2πr=nλ (standing wave); ν≈3.1×1015Hz.
Solution
(a) Bohr's postulate: only those orbits are stable (non-radiating) for which the angular momentum is an integral multiple of 2πh: mvr=2πnh. De-Broglie's hypothesis explains this: the electron is a matter wave, and an orbit is stable only if its circumference contains a whole number of wavelengths (2πr=nλ), forming a non-radiating standing wave (see figure). (b) Energy absorbed: