CBSE Class 12 · 2003 · All India · Chemical KineticsShort Answer

WhatsApp Email
What is known as 'activation energy'? How is the activation energy affected by (i) the use of a catalyst and (ii) a rise in temperature?

Solution

Activation energy is the minimum extra energy, above their average energy, that reactant molecules must acquire to form the activated complex and change into products.
(i) A catalyst lowers the activation energy by providing an alternative reaction path.
(ii) A rise in temperature does not change ; it increases the fraction of molecules having energy , which is why the rate increases.

CBSE Class 12 Board · 2003 · All India · Subjective

More board questions on Chemical Kinetics

  1. The rate of a reaction increases sixteen times when the concentration of the reactant increases four times. The order of the reaction is
    CBSE 2024View solution →
  2. Assertion (A): The units of the rate constant of a zero order reaction and of the rate of reaction are the same.
    Reason (R): In a zero order reaction, the rate of reaction is independent of the concentration of the reactants.
    CBSE 2024View solution →
  3. Show that in the case of a first order reaction, the time taken for completion of 99% of the reaction is twice the time required for 90% completion of the reaction. (log 10 = 1)
    CBSE 2024View solution →
  4. The rate constant of a reaction quadruples when the temperature changes from 300 K to 320 K. Calculate the activation energy for this reaction. (log 2 = 0.30, log 4 = 0.60, 2.303 R = 19.15 J K mol)
    CBSE 2024View solution →
  5. What happens to the rate constant k and the activation energy E as the temperature of a chemical reaction is increased? Justify.
    CBSE 2023View solution →
  6. (a) For the reaction at 318 K, calculate the rate of reaction if the rate of disappearance of NO(g) is M s.
    (b) For a first order reaction, derive the relationship t = 2 t …
    CBSE 2023View solution →