But-2-yne is reacted separately with one mole of Hydrogen as shown below:
(A) A is more soluble than B.
(B) The boiling point & melting point of A are higher and lower than B respectively.
(C) A is more polar than B because dipole moment of A is zero.
(D) adds easily to B than A .
Identify the incorrect statements from the options given below :-
(A) A is more soluble than B.
(B) The boiling point & melting point of A are higher and lower than B respectively.
(C) A is more polar than B because dipole moment of A is zero.
(D) adds easily to B than A .
Identify the incorrect statements from the options given below :-
- (A)B and C only
- (B)B, C and D only
- (C)A, C and D only
- (D)A and B only
Solution
reduces but-2-yne to -but-2-ene (); gives -but-2-ene (). () has a net dipole and is polar; () is symmetric with zero dipole. Statement (C) is self-contradictory — it says is more polar \emph{because} its dipole moment is zero — so (C) is incorrect. Statement (D) has no valid basis since adds readily to both alkenes. Statements (A) and (B) are correct. The incorrect statements are therefore (C) and (D), but no option lists exactly ; hence the question is a bonus with no correct option.
JEE Main · 2023 · 01 Feb 2023 · Shift 1 · Single correct option