JEE Main · 2022 · 26 Jul 2022 · Shift 2 · Equilibrium

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Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A :Phenolphthalein is a pH dependent indicator, remains colourless in acidic solution and gives pink colour in basic medium
Reason R : Phenolphthalein is a weak acid. It doesn't dissociate in basic medium.

In the light of the above statements, choose the most appropriate answer from the options given below:
  1. (A)Both A and R are true and R is the correct explanation of A
  2. (B)Both A and R are true but R is NOT the correct explanation of A .
  3. (C)A is true but R is false✓ Correct
  4. (D)A is false but R is true

Answer: (C)

Solution

Assertion A is correct: Phenolphthalein is colorless in acidic solution and pink in basic medium. However, Reason R is false: Phenolphthalein is a weak acid that DOES dissociate in basic medium. The dissociation equilibrium shifts to the right in basic conditions, producing the pink-colored phenolate ion (). Therefore, A is true but R is false.

JEE Main · 2022 · 26 Jul 2022 · Shift 2 · Single correct option

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