Consider the following reaction : \[ 2 \mathrm{HSO}_{4}^{-}(\mathrm{aq}) \xrightarrow[\text { (2) Hydrolysis }]{\text { (1) Electrolysis }} 2 \mathrm{HSO}_{4}^{-}+2 \mathrm{H}^{+}+\mathbf{A} \] The dihedral angle in product $\mathbf{A}$ in its solid phase at 110 K is :

JEE Main · 2022 · 26 Jun 2022 · Shift 1 · Hydrogen

Consider the following reaction :

2 HSO_{4}^{-} (aq) (1) Electrolysis (2) Hydrolysis 2 HSO_{4}^{-} + 2 H^{+} + A

The dihedral angle in product

A

in its solid phase at 110 K is :

Answer: (C)

The electrolysis of

HSO_{4}^{-}

followed by hydrolysis produces hydrogen peroxide (

H_{2} O_{2}

) as product A.

In the solid phase at 110 K,

H_{2} O_{2}

has an open-book structure with a dihedral angle of approximately 90.2° between the two O-H bonds.

JEE Main · 2022 · 26 Jun 2022 · Shift 1 · Single correct option