A compound 'X' is acidic and it is soluble in NaOH solution, but insoluble in NaHCOX3 solution. Compound 'X' also gives violet colour with neutral FeClX3 solution. The compound 'X' is:
(A)(see structure)
(B)(see structure)✓ Correct
(C)(see structure)
(D)(see structure)
Answer: (B)
Solution
Compound X is phenol. Phenols are weakly acidic and soluble in strong bases like NaOH but not in weak bases like NaHCOX3 (unlike carboxylic acids which dissolve in both). The violet color with neutral FeClX3 is a characteristic test for phenols, confirming the presence of the phenolic -OH group. Cyclohexanol and benzyl alcohol do not give this test.
JEE Main · 2022 · 29 Jul 2022 · Shift 1 · Single correct option