The structure is CH3−CH=CH−C≡C−H. Every bond between two atoms contains exactly one sigma bond whatever its order, the second and third bonds of a double or triple bond being π. The chain therefore gives four carbon-carbon sigma bonds, and the hydrogens add six more: three on the methyl carbon, one on each of the two doubly bonded carbons and one on the terminal alkyne carbon. The number of sigma bonds is 10.