JEE Main · 2021 · 16 Mar 2021 · Shift 1 · p-Block Elements

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Match List - I with List - II

List - I
Name of oxo acid
(a) Hypophosphorous acid
(b) Orthophosphoric acid
(c) Hypophosphoric acid
(d) Orthophosphorous acid

List - II
Oxidation state of "P"
(i) +5
(ii) +4
(iii) +3
(iv) +2
(v) +1

Choose the correct answer from the options given below:
  1. (A)(a) - (v), (b)-(iv), (c)-(ii), (d)-(iii)
  2. (B)(a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
  3. (C)(a) -(iv), (b)-(v), (c)-(ii), (d)-(iii)
  4. (D)(a) - (v), (b)-(i), (c)-(ii), (d)-(iii)✓ Correct

Answer: (D)

Solution

The oxidation state of phosphorus follows from the formula once hydrogen is taken as and oxygen as .
Hypophosphorous acid is , which gives .
Orthophosphoric acid is , which gives .
Hypophosphoric acid is , with a P-P bond, and each phosphorus is .
Orthophosphorous acid is , which gives .
So hypophosphorous acid pairs with , orthophosphoric acid with , hypophosphoric acid with and orthophosphorous acid with .

JEE Main · 2021 · 16 Mar 2021 · Shift 1 · Single correct option

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