The value of the 'spin only' magnetic moment for one of the following configurations is 2.84 BM. The correct one is
(A)d4 (in strong ligand filed)✓ Correct
(B)d4 (in weak ligand field)
(C)d3 (in weak as well as in strong fields)
(D)d5 (in strong ligand field)
Answer: (A)
Solution
A spin-only moment of 2.84 BM points, through μ=n(n+2), to n=2 unpaired electrons, since 2×4=8≈2.83. A d4 ion in a strong field pairs electrons into the lower t2g set, reaching t2g4eg0 with two of the four electrons paired and two left unpaired, which gives exactly n=2. Weak-field d4 would keep all four unpaired and d3 always keeps three, so the match is d4 in a strong field.
JEE Main · 2005 · 08 May 2005 · Offline · Single correct option