JEE Main · 2004 · 24 Apr 2004 · Offline · Solid State

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The soldiers of Napolean army while at Alps during freezing winter suffered a serious problem as regards to the tin buttons of their uniforms. White metallic tin buttons got converted to grey powder. This transformation is related to
  1. (A)an interaction with nitrogen of the air at very low temperatures
  2. (B)an interaction with water vapour contained in the humid air
  3. (C)a change in the partial pressure of oxygen in the air
  4. (D)a change in the crystalline structure of tin✓ Correct

Answer: (D)

Solution

This is the classic case of tin pest. The ordinary white, metallic form of tin, -tin, is stable only above about ; below that it slowly turns into grey -tin, a crumbly non-metallic powder. The transformation is a change in the crystal structure of the element itself, from the tetragonal white form to the diamond-type cubic grey form, and the bitter Alpine cold is what set it off in the soldiers' buttons.

JEE Main · 2004 · 24 Apr 2004 · Offline · Single correct option

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