JEE Main · 2004 · 24 Apr 2004 · Offline · d and f Block Elements

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Cerium is an important member of the lanthanoids. Which of the following statements about cerium is incorrect?
  1. (A)The common oxidation states of cerium are +3 and +4
  2. (B)Cerium (IV) acts as an oxidizing agent
  3. (C)The +4 oxidation state of cerium is not known in solutions✓ Correct
  4. (D)The +3 oxidation state of cerium is more stable than the +4 oxidation state

Answer: (C)

Solution

Cerium's usual oxidation states are and , and cerium(IV) is a well-known, strong oxidising agent, the couple sitting around . Crucially, is perfectly familiar in aqueous solution, so the claim that the state is unknown in solution is the false one. That the state is the more stable of the two is itself a correct remark.

JEE Main · 2004 · 24 Apr 2004 · Offline · Single correct option

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