JEE Advanced · 2025 · 18 May 2025 · Paper 2 · Hydrocarbons

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For the reaction sequence given below, the correct statement(s) is(are)
  1. (A)P is optically active.
  2. (B)S gives Bayer's test.✓ Correct
  3. (C)Q gives effervescence with aq. .✓ Correct
  4. (D)R is an alkyne.

Answer: (B), (C)

Solution

Analyzing the reaction sequence:

(A) is incorrect: P does not have a chiral center, so it is not optically active.

(B) is correct: S contains a C=C double bond and gives a positive Baeyer's test (decolorization of KMnO₄ solution due to oxidation of the alkene to a diol).

(C) is correct: Q is a carboxylic acid, which reacts with aqueous NaHCO₃ to produce CO₂ gas (effervescence).

(D) is incorrect: R is not an alkyne based on the reaction pathway shown.

JEE Advanced · 2025 · 18 May 2025 · Paper 2 · One or more correct options

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