JEE Advanced · 2022 · 28 Aug 2022 · Paper 2 · Polymers

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Among the following, the correct statement(s) about polymers is(are)
  1. (A)The polymerization of chloroprene gives natural rubber.
  2. (B)Teflon is prepared from tetrafluoroethene by heating it with persulphate catalyst at high pressures.✓ Correct
  3. (C)PVC are thermoplastic polymers.✓ Correct
  4. (D)Ethene at 350-570 K temperature and 1000-2000 atm pressure in the presence of a peroxide initiator yields high density polythene.

Answer: (B), (C)

Solution

Option (A): Polymerization of chloroprene gives neoprene (synthetic rubber), not natural rubber. Natural rubber is polyisoprene. Incorrect.

Option (B): Teflon (polytetrafluoroethylene) is prepared by polymerizing tetrafluoroethene using persulphate catalyst at high pressure and temperature. Correct.

Option (C): PVC (polyvinyl chloride) is a thermoplastic polymer that softens on heating and hardens on cooling. Correct.

Option (D): Ethene at 350-570 K and 1000-2000 atm with peroxide initiator yields low-density polyethene (LDPE), not high-density polyethene. HDPE is made at lower pressure with Ziegler-Natta catalyst. Incorrect.

JEE Advanced · 2022 · 28 Aug 2022 · Paper 2 · One or more correct options

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