JEE Advanced · 2017 · 21 May 2017 · Paper 1 · General Organic Chemistry

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The IUPAC name(s) of the following compound is(are)
  1. (A)1-chloro-4-methylbenzene✓ Correct
  2. (B)4-chlorotoluene✓ Correct
  3. (C)4-methylchlorobenzene
  4. (D)1-methyl-4-chlorobenzene

Answer: (A), (B)

Solution

The compound is para-chlorotoluene (methyl and chloro groups at positions 1 and 4 on benzene).

Option A: 1-chloro-4-methylbenzene is correct (numbering starts from Cl).

Option B: 4-chlorotoluene is correct (toluene with Cl at position 4).

Option C: 4-methylchlorobenzene is incorrect (chlorobenzene is the parent, but methyl should be numbered, not just stated as "4-methyl").

Option D: 1-methyl-4-chlorobenzene is incorrect (benzene derivatives don't use "1-methyl"; toluene is the parent when methyl is present).

Correct answers: A, B

JEE Advanced · 2017 · 21 May 2017 · Paper 1 · One or more correct options

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