JEE Advanced · 2015 · 24 May 2015 · Paper 1 · Redox Reactions and Electrochemistry

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Copper is purified by electrolytic refining of blister copper. The correct statement(s) about this process is (are)
  1. (A)Impure Cu strip is used as cathode
  2. (B)Acidified aqueous is used as electrolyte✓ Correct
  3. (C)Pure Cu deposits at cathode✓ Correct
  4. (D)Impurities settle as anode-mud✓ Correct

Answer: (B), (C), (D)

Solution

In electrolytic refining of copper:
  • Anode: Impure copper (blister copper)
  • Cathode: Pure copper strip
  • Electrolyte: Acidified solution

During electrolysis, copper from the anode dissolves and deposits as pure copper at the cathode. Impurities either dissolve or settle below the anode as anode mud.

(A) Incorrect: Impure Cu is the anode, not cathode.
(B) Correct: Acidified is the electrolyte.
(C) Correct: Pure Cu deposits at the cathode.
(D) Correct: Impurities settle as anode mud.

Correct answers: (B), (C) and (D).

JEE Advanced · 2015 · 24 May 2015 · Paper 1 · One or more correct options

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