The IUPAC name of the following compound is
(see structure)
(see structure)

- (A)4-Bromo-3-cyanophenol
- (B)2-Bromo-5-hydroxybenzonitrile✓ Correct
- (C)2-Cyano-4-hydroxybromobenzene
- (D)6-Bromo-3-hydroxybenzonitrile
Answer: (B)
Solution
In IUPAC nomenclature, the principal functional group gets the lowest number. For this compound:
Therefore, the IUPAC name is 2-Bromo-5-hydroxybenzonitrile.
The answer is (B).
- The cyano group (–CN) has the highest priority and is designated as benzonitrile
- Numbering starts from the carbon bearing the CN group (position 1)
- The Br is at position 2
- The OH is at position 5
Therefore, the IUPAC name is 2-Bromo-5-hydroxybenzonitrile.
The answer is (B).
JEE Advanced · 2009 · 12 Apr 2009 · Paper 1 · Single correct option