The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in non-luminous flame under hot condition in borax bead test is
- (A)
- (B)✓ Correct
- (C)
- (D)
Answer: (B)
Solution
has the configuration ; in an octahedral field there is no alternative arrangement for eight d-electrons whether the ligand is weak- or strong-field, so its electronic configuration — and the magnetic/spectral behaviour that follows from it — is essentially unaffected by the identity of the ligand. In the borax bead test, the nickel metaborate formed under a hot, non-luminous (oxidising) flame gives the characteristic violet-coloured bead.
JEE Main · 2025 · 28 Jan 2025 · Shift 1 · Single correct option