JEE Main · 2024 · 08 Apr 2024 · Shift 2 · Haloalkanes and Haloarenes

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Given below are two statements :

Statement (I): reactions are 'stereospecific', indicating that they result in the formation only one stereo-isomers as the product.
Statement (II) : reactions generally result in formation of product as racemic mixtures. In the light of the above statements, choose the correct answer from the options given below :
  1. (A)Statement I is true but Statement II is false
  2. (B)Statement I is false but Statement II is true
  3. (C)Both Statement I and Statement II is true✓ Correct
  4. (D)Both Statement I and Statement II is false

Answer: (C)

Solution

Statement I: proceeds through backside attack (Walden inversion) with complete stereospecificity, giving a single, defined stereochemical outcome — true.
Statement II: proceeds via a planar carbocation intermediate attacked from either face, generally giving a racemic (or near-racemic) mixture — true.
Both statements are true.

JEE Main · 2024 · 08 Apr 2024 · Shift 2 · Single correct option

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