JEE Main · 2024 · 01 Feb 2024 · Shift 1 · Practical and Analytical Chemistry

WhatsApp Email
Given below are two statements:

Statement (I): Potassium hydrogen phthalate is a primary standard for standardisation of sodium hydroxide solution.
Statement (II): In this titration phenolphthalein can be used as indicator.
In the light of the above statements, choose the most appropriate answer from the options given below:
  1. (A)Both Statement I and Statement II are correct✓ Correct
  2. (B)Statement I is correct but Statement II is incorrect
  3. (C)Statement I is incorrect but Statement II is correct
  4. (D)Both Statement I and Statement II are incorrect

Answer: (A)

Solution

Potassium hydrogen phthalate (KHP) is a primary standard for standardising NaOH solution because it is stable, non-hygroscopic, of high purity and known composition. In this acid-base titration (weak acid vs strong base), the equivalence point is on the basic side, so phenolphthalein (colour change range pH 8.3-10) is the correct indicator. Both statements are correct.

JEE Main · 2024 · 01 Feb 2024 · Shift 1 · Single correct option

More JEE Main questions on Practical and Analytical Chemistry

  1. Consider the following reactions.
    (Hot solution)
    …
    JEE Main 2026View solution →
  2. In Carius method, 0.75 g of an organic compound gave 1.2 g of barium sulphate, find percentage of sulphur (molar mass ). Molar mass of barium sulphate is .
    JEE Main 2026View solution →
  3. Sodium fusion extract of an organic compound (Y) with and chlorine water gives violet color to the layer. 0.15 g of gave 0.12 g of the silver halide precipitate in Carius method. Percentage of halogen in the compound …
    JEE Main 2026View solution →
  4. When 1 g of compound ( X ) is subjected to Kjeldahl's method for estimation of nitrogen, 15 was neutralized by ammonia evolved. The percentage of nitrogen in compound is :
    JEE Main 2026View solution →
  5. Identify the correct statements:
    A. Hydrated salts can be used as primary standard.
    B. Primary standard should not undergo any reaction with air.
    C. Reactions of primary standard with another substance should be instantaneous and stoichiometric.
    D. Primary standard should not be …
    JEE Main 2026View solution →
  6. Match List-I with List-II.

    List-I: Functional group (detection)
    (A) Unsaturation (Baeyer's test)
    (B) Alcoholic group (Ceric ammonium nitrate test)
    (C) Aldehyde group (Tollen's reagent)
    (D) Phenolic group ( test)

    List-II: Change observed during detection
    (I) Red co …
    JEE Main 2026View solution →