The covalency and oxidation state respectively of boron in [BF4]−, are
(A)4 and 3✓ Correct
(B)4 and 4
(C)3 and 4
(D)3 and 5
Answer: (A)
Solution
In [BF4]−, boron forms four covalent bonds with four fluorine atoms, so the covalency is 4. To find the oxidation state: let the oxidation state of B be x. Since each F has oxidation state −1 and the overall charge is −1: x+4(−1)=−1, giving x=+3. Therefore, covalency = 4 and oxidation state = +3.
JEE Main · 2023 · 13 Apr 2023 · Shift 2 · Single correct option