For OF2 molecule consider the following: (A) Number of lone pairs on oxygen is 2. (B) FOF angle is less than 104.5∘. (C) Oxidation state of O is -2. (D) Molecule is bent 'V' shaped. (E) Molecular geometry is linear.
Correct options are:
(A)C, D, E only
(B)B, E, A only
(C)A, C, D only
(D)A, B, D only✓ Correct
Answer: (D)
Solution
Oxygen in OF2 makes two bonds to fluorine, using four of its six valence electrons and leaving two lone pairs, so the count of two lone pairs holds. With two bond pairs and two lone pairs the electron set is tetrahedral and the molecule is bent, a V-shape rather than linear. Because fluorine is more electronegative than oxygen, oxygen carries the oxidation state +2 here, not −2. The strong repulsion of the two lone pairs squeezes the F-O-F angle below the 104.5∘ of water, to about 103∘. The correct statements are that oxygen bears two lone pairs, that the F-O-F angle is less than 104.5∘, and that the molecule is bent.
JEE Main · 2023 · 30 Jan 2023 · Shift 1 · Single correct option