JEE Main · 2022 · 27 Jun 2022 · Shift 1 · Classification of Elements and Periodicity

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Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason(R)

Assertion (A): The ionic radii of and are same.

Reason (R) : Both and are isoelectronic species

In the light of the above statements, choose the correct answer from the options given below
  1. (A)Both (A) and (R) are true and (R) is the correct explanation of (A)
  2. (B)Both (A) and (R) are true but (R) is not the correct explanation of (A)
  3. (C)(A) is true but (R) is false
  4. (D)(A) is false but (R) is true✓ Correct

Answer: (D)

Solution

Both and are isoelectronic with 10 electrons each (electronic configuration: ), so the reason is true. However, the ionic radius of is larger than that of because has a higher nuclear charge (12 protons vs 8 protons), which pulls the electrons closer. Therefore, the assertion is false but the reason is true.

JEE Main · 2022 · 27 Jun 2022 · Shift 1 · Single correct option

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