JEE Main · 2021 · 26 Aug 2021 · Shift 1 · Redox Reactions and Electrochemistry

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These are physical properties of an element
(A) Sublimation enthalpy
(B) Ionisation enthalpy
(C) Hydration enthalpy
(D) Electron gain enthalpy

The total number of above properties that affect the reduction potential is ______ (Integer answer)

Answer: 3

Solution

The standard reduction potential of a metal ion-metal couple is fixed by the energy cycle that takes the solid metal to its hydrated ion in solution: atomisation of the solid, which costs the sublimation enthalpy; removal of electrons from the gaseous atom, which costs the ionisation enthalpy; and solvation of the gaseous ion, which releases the hydration enthalpy. Electron gain enthalpy belongs to the formation of a gaseous anion from a gaseous atom and plays no part in this cycle. The number of the listed properties that affect the reduction potential is .

JEE Main · 2021 · 26 Aug 2021 · Shift 1 · Integer answer

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