Match List - I with List - II.
List - I
Electronic configuration of elements
(a)
(b)
(c)
(d)
List - II
in
(i) 801
(ii) 899
(iii) 1314
(iv) 1402
Choose the most appropriate answer from the options given below:
List - I
Electronic configuration of elements
(a)
(b)
(c)
(d)
List - II
in
(i) 801
(ii) 899
(iii) 1314
(iv) 1402
Choose the most appropriate answer from the options given below:
Answer: A → II, B → III, C → IV, D → I
Solution
The four configurations belong to beryllium , oxygen , nitrogen and boron .
Across the second period the ionisation enthalpy rises with nuclear charge, but two places break the rise. Boron falls below beryllium because its outermost electron sits in a orbital that is screened by the filled pair and is held less firmly than a electron. Oxygen falls below nitrogen because oxygen loses one electron of its only paired orbital and so relieves the repulsion between that pair, whereas nitrogen would have to break its stable half filled set.
The order is therefore boron beryllium oxygen nitrogen, which assigns to , to , to and to .
Across the second period the ionisation enthalpy rises with nuclear charge, but two places break the rise. Boron falls below beryllium because its outermost electron sits in a orbital that is screened by the filled pair and is held less firmly than a electron. Oxygen falls below nitrogen because oxygen loses one electron of its only paired orbital and so relieves the repulsion between that pair, whereas nitrogen would have to break its stable half filled set.
The order is therefore boron beryllium oxygen nitrogen, which assigns to , to , to and to .
JEE Main · 2021 · 26 Feb 2021 · Shift 1 · Match the columns