JEE Main · 2020 · 05 Sep 2020 · Shift 1 · Surface Chemistry

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Identify the correct molecular picture showing what happens at the critical micellar concentration (CMC) of an aqueous solution of a surfactant
(● polar head; ▬ non-polar tail ; · water).
  1. (A)(B)
  2. (B)(A)
  3. (C)(C)
  4. (D)(D)✓ Correct

Answer: (D)

Solution

At the critical micelle concentration the surfactant molecules first gather into micelles. In water the non-polar tails cluster together in the interior, shielded from the solvent, while the polar heads point outward into the water, which minimises the free energy of the system. The picture showing tails drawn inward and polar heads facing the surrounding water is the correct one.

JEE Main · 2020 · 05 Sep 2020 · Shift 1 · Single correct option

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