Following figure shows two processes A and B for a gas. If ΔQA and ΔQB are the amount of heat absorbed by the system in two cases, and ΔUA and ΔUB are changes in internal energies, respectively, then:
(A)ΔQA=ΔQB;ΔUA=ΔUB
(B)ΔQA>ΔQB;ΔUA=ΔUB✓ Correct
(C)ΔQA<ΔQB;ΔUA<ΔUB
(D)ΔQA>ΔQB;ΔUA>ΔUB
Answer: (B)
Solution
Internal energy is a state function, so since both paths start and end at the same states, ΔUA=ΔUB. On the P-V diagram path A encloses the larger area and therefore does more work, WA>WB. Applying the first law ΔQ=ΔU+W with equal ΔU but larger work for A gives ΔQA>ΔQB while ΔUA=ΔUB.
JEE Main · 2019 · 09 Apr 2019 · Shift 1 · Single correct option