JEE Main · 2019 · 12 Apr 2019 · Shift 2 · Classification of Elements and Periodicity

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In comparison to boron, berylium has:
  1. (A)greater nuclear charge and greater first ionisation enthalpy
  2. (B)lesser nuclear charge and lesser first ionisation enthalpy
  3. (C)greater nuclear charge and lesser first ionisation enthalpy
  4. (D)lesser nuclear charge and greater first ionisation enthalpy✓ Correct

Answer: (D)

Solution

Beryllium () carries a smaller nuclear charge than boron (), yet its first ionisation enthalpy is larger. The reason is that beryllium's electron leaves a filled, stable shell, whereas boron loses a single, loosely held electron. So beside boron, beryllium has lesser nuclear charge but greater first ionisation enthalpy.

JEE Main · 2019 · 12 Apr 2019 · Shift 2 · Single correct option

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