JEE Advanced · 2015 · 24 May 2015 · Paper 2 · Chapter_pending

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In the following reactions, the product S is
  1. (A)(see structure)
    ✓ Correct
  2. (B)(see structure)
  3. (C)(see structure)
  4. (D)(see structure)

Answer: (A)

Solution

The reaction sequence shows a Skraup synthesis or similar quinoline formation. The starting material undergoes cyclization with glycerol and an oxidizing agent to form a quinoline derivative. Based on the reaction conditions and the structure of the starting material (a methylated aniline derivative), the product S is the quinoline with the methyl group at the appropriate position. The correct structure is option (B).

JEE Advanced · 2015 · 24 May 2015 · Paper 2 · One or more correct options

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