JEE Main · 2024 · 04 Apr 2024 · Shift 2 · Chemical Bonding and Molecular Structure

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The number of species from the following that have pyramidal geometry around the central atom is
, , ,
  1. (A)4
  2. (B)3
  3. (C)1✓ Correct
  4. (D)2

Answer: (C)

Solution

Considering the geometry around the central sulfur atom in each species:
  • (sulfite): S has 3 bonded O atoms plus one lone pair — pyramidal (AXE), like .
  • (thiosulfate), (sulfate) and (pyrosulfate): in each of these the central S atom is bonded to four groups (four O atoms, or three O atoms plus the terminal S in thiosulfate) with no lone pair — tetrahedral (AX) about that centre.
Only is pyramidal, so the count is 1.
(This question was flagged for possible ambiguity depending on whether "geometry" is read as molecular shape or electron-pair geometry; the NTA/Allen key treats only the sulfite ion as pyramidal, giving 1.)
Structure Structure diagrams
Structure diagrams

JEE Main · 2024 · 04 Apr 2024 · Shift 2 · Single correct option

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