The number of species from the following that have pyramidal geometry around the central atom is S2O32−, SO42−, SO32−, S2O72−
(A)4
(B)3
(C)1✓ Correct
(D)2
Answer: (C)
Solution
Considering the geometry around the central sulfur atom in each species:
SO32− (sulfite): S has 3 bonded O atoms plus one lone pair — pyramidal (AX3E), like NH3.
S2O32− (thiosulfate), SO42− (sulfate) and S2O72− (pyrosulfate): in each of these the central S atom is bonded to four groups (four O atoms, or three O atoms plus the terminal S in thiosulfate) with no lone pair — tetrahedral (AX4) about that centre.
Only SO32− is pyramidal, so the count is 1. (This question was flagged for possible ambiguity depending on whether "geometry" is read as molecular shape or electron-pair geometry; the NTA/Allen key treats only the sulfite ion as pyramidal, giving 1.)Structure diagrams
JEE Main · 2024 · 04 Apr 2024 · Shift 2 · Single correct option