Vanillin compound obtained from vanilla beans, has total sum of oxygen atoms and π electrons is ____
Answer: 11
Solution
Vanillin (4-hydroxy-3-methoxybenzaldehyde, C8H8O3) has 3 oxygen atoms (the aldehyde O, the phenolic –OH oxygen, and the methoxy ether O). Its π system: the benzene ring contributes 3 C=C π bonds (6 π electrons), and the aldehyde group contributes 1 C=O π bond (2 π electrons), giving 4 π bonds =8π electrons. Sum of oxygen atoms and π electrons =3+8=11.