JEE Main · 2025 · 24 Jan 2025 · Shift 2 · Classification of Elements and Periodicity

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The successive 5 ionisation energies of an element are 800 , 2427, 3658, 25024 and , respectively. By using the above values predict the group in which the above element is present :
  1. (A)Group 2
  2. (B)Group 13✓ Correct
  3. (C)Group 4
  4. (D)Group 14

Answer: (B)

Solution

Successive ionization energies climb steadily as electrons are removed from the same shell, but jump sharply once an electron must be pulled from a completed, lower-lying shell. Here through (800, 2427, 3658 kJ/mol) rise only modestly, but leaps to 25024 kJ/mol — nearly a sevenfold jump.

This sharp discontinuity right after the third electron shows that the element has exactly three electrons in its valence shell; the fourth electron has to be extracted from a stable, noble-gas-like core, which demands far more energy. Three valence electrons place the element in Group 13.

JEE Main · 2025 · 24 Jan 2025 · Shift 2 · Single correct option

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