JEE Main · 2024 · 30 Jan 2024 · Shift 1 · Aldehydes Ketones and Carboxylic Acids

An organic compound "P" of molecular formula ${\mathrm{C}}_6{\mathrm{H}}_{12}{\mathrm{O}}_3$ gives positive iodoform test but negative Tollen's test. When "P" is treated with dilute acid, it produces "Q". "Q" gives positive Tollen's test and also iodoform test. The structure of …

Match List-I with List-II.

List-I (Reaction Name - Involving aldehydes):
I. Etard Reaction
II. Rosenmund Reduction
III. Gatterman-Koch Reaction
IV. Stephen Reaction

List-II (Reagents):
A. ${\mathrm{H}}_2$, Pd-${\mathrm{BaSO}}_4$
B. ${\mathrm{SnCl}}_2$, HCl
C. …

The compound A, ${\mathrm{C}}_8{\mathrm{H}}_8{\mathrm{O}}_2$ reacts with acetophenone to form a single product via cross-Aldol condensation. The compound A on reaction with conc. NaOH forms a substituted benzyl alcohol as

' $x$ ' is the product which is obtained from propanenitrile and stannous chloride in the presence of hydrochloric acid followed by hydrolysis. ' y ' is the product which is obtained from the but-2-ene by the ozonolysis followed by hydrolysis. From the following, which product is …

From the given following (A to D) cyclic structures, those which will not react with Tollen's reagent are :

Iodoform test can differentiate between
A. Methanol and Ethanol
B. ${\mathrm{CH}}_3\mathrm{COOH}$ and ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{COOH}$
C. Cyclohexene and cyclohexanone
D. Diethyl ether and Pentan-3-one
E. Anisole and acetone

Choose the correct answer from the …