JEE Main · 2022 · 29 Jul 2022 · Shift 1 · Compounds Containing Nitrogen

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Which among the following represent reagent 'A'?
  1. (A)(see structure)
    ✓ Correct
  2. (B)(see structure)
  3. (C)(see structure)
  4. (D)(see structure)

Answer: (A)

Solution

The reaction shown is a coupling reaction forming an azo dye. Reagent A must be 2-naphthol (β-naphthol), which couples with diazonium salts at the 1-position (ortho to the -OH group) to form colored azo compounds. This is a classic electrophilic aromatic substitution where the activated naphthalene ring couples with the diazonium ion.

JEE Main · 2022 · 29 Jul 2022 · Shift 1 · Single correct option

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