General Organic Chemistry — JEE Main PYQs

194 previous year questions on General Organic Chemistry (Chemistry), newest first. Open any question for its complete step-by-step solution.

  1. Functional group present in sulphonic acid is :
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  2. Which of the following is metamer of the given compound (X) ?
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  3. The incorrect statement regarding the geometrical isomers of 2-butene is:
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  4. Number of carbocation from the following that are not stabilized by hyperconjugation is ______.
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  5. The shape of carbocation is :
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  6. IUPAC name of following hydrocarbon (X) is :
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  7. Total number of optically active compounds from the following is ____ .
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  8. Total number of aromatic compounds among the following compounds is ____.
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  9. Given below are two statements:

    Statement I:
    IUPAC name of Compound A is 4-chloro-1, 3-dinitrobenzene:

    Statement II:
    IUPAC name of Compound B is 4-ethyl-2-methylaniline.

    In the light of the above statements, choose the most appropriate answer from the options given below:
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  10. In the given compound, the number of carbon atom/s is ______ .
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  11. Which of the following are aromatic?
    A.
    B.
    C.
    D.
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  12. The number of optical isomers in following compound is : ______.
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  13. Relative stability of the contributing structures is :
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  14. How many compounds among the following compounds show inductive, mesomeric as well as hyperconjugation effects?
    ,
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  15. The correct stability order of the following resonance structures of is
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  16. Total number of stereo isomers possible for the given structure:
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  17. Highest enol content will be shown by :
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  18. IUPAC name of following compound (P) is :
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  19. Among the given organic compounds, the total number of aromatic compounds is
    (A) (see structure)
    (B) (see structure)
    (C) (see structure)
    (D) (see structure)
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  20. The functional group that shows negative resonance effect is:
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  21. Total number of isomeric compounds (including stereoisomers) formed by monochlorination of 2-methylbutane is ____.
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  22. Ionic reactions with organic compounds proceed through:
    (A) Homolytic bond cleavage
    (B) Heterolytic bond cleavage
    (C) Free radical formation
    (D) Primary free radical
    (E) Secondary free radical

    Choose the correct answer from the options given below:
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  23. Number of optical isomers possible for 2-chlorobutane ____
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  24. The order of relative stability of the contributing structure is:

    Choose the correct answer from the options given below:
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  25. The molecular formula of second homologue in the homologous series of mono carboxylic acids is ______.
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  26. Bond line formula of HOCH(CN)₂ is:
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  27. The incorrect statement regarding conformations of ethane is:
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  28. Total number of compounds with Chiral carbon atoms from following is .
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  29. The difference in energy between the actual structure and the lowest energy resonance structure for the given compound is
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  30. The interaction between bond and lone pair of electrons present on an adjacent atom is responsible for
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  31. Number of compounds among the following which contain sulphur as heteroatom is ____.

    Furan, Thiophene, Pyridine, Pyrrole, Cysteine, Tyrosine
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  32. The ascending acidity order of the following H atoms is
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  33. According to IUPAC system, the compound is named as
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  34. Which one of the following will show geometrical isomerism?
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  35. A species having carbon with sextet of electrons and can act as electrophile is called
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  36. Given below are two statements:
    Statement I: IUPAC name of is 7-hydroxyheptan-2-one.
    Statement II: 2-oxoheptan-7-ol is the correct IUPAC name for above compound.
    In the light of th …
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  37. Which of the following molecule/species is most stable?
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  38. Structure of 4-Methylpent-2-enal is
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  39. Identify structure of 2,3-dibromo-1-phenylpentane.
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  40. IUPAC name of following compound is
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  41. The correct stability order of carbocations is
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  42. Number of geometrical isomers possible for the given structure is/are ____.
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  43. 2-chlorobutane (isomers) Total number of optically active isomers shown by , obtained in the above reaction is ____.
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  44. The correct IUPAC nomenclature for the following compound is
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  45. The decreasing order of hydride affinity for following carbocations is:
    A. (see structure)
    B. (see structure)
    C. (see structure)
    D. (see structure)
    Choose the correct answer from the options given below:
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  46. The number of hyperconjugation structures involved to stabilize carbocation formed in the above reaction is ____.
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  47. Given below are two statements:
    Statement I: Tropolone is an aromatic compound and has electrons.
    Statement II: electrons of group in tropolone is involved in aromaticity.
    In the light of the above statements, choose the correct answer …
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  48. Resonance in carbonate ion is

    Which of the following is true?
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  49. The total number of chiral compound/s from the following is ____.
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  50. Which of the following conformations will be the most stable?
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